نوع مقاله : مقاله پژوهشی

نویسندگان

دانشگاه ارومیه

چکیده

فاضلاب شهری به عنوان یک منبع بالقوه غنی از فسفر است. از آنجا که  منابع  تجدید ناپذیر سنگ فسفات در جهان محدود است لذا بازیابی فسفر از لجن فاضلاب به صورت استرووایت یا منیزیم آمونیوم فسفات (MgNH4PO4.6H2O) به عنوان کود کندرها در سراسر جهان مورد توجه قرار گرفته است. در این پژوهش رسوب فسفر از لجن فاضلاب خانگی به صورت استرووایت و کامپوزیت استرووایت/بیوچار با فرایند هضم-جذب در حضور اسید سولفوریک (2/0 نرمال) و نسبت مولی /NH4+­­Mg2+/PO43-  2:1:1 و pH برابر 5/8 انجام شد. بطوریکه برای تهیه استرووایت و کامپوزیت استرووایت/بیوچار از نسبت­های متفاوت بیوچار ضایعات هرس انگور به استرووایت شامل، 100:0، 75:25، 50:50 و 25:75 استفاده شد و برخی از ویژگی­های فیزیکوشیمیایی آن­ها مشخص گردید. سنتیک رهاسازی فسفر از نمونه ها در زمان­های 24 ساعت، 3، 5، 10، 14، 28، 42، 56 و 84 روز در آب مقطر، اسید سیتریک (20g/L ) و HCl (5/0 مولار) بررسی شد. در بررسی سنتیک نمونه­ها، سرعت رهاسازی عناصر فسفر، منیزیم و نیتروژن با افزایش زمان تماس نمونه­ها با آب، اسید سیریک و HCL افزایش یافت و داده های سنتیک در آب و اسید سیتریک برازش بهتری با معادله درجه اول (99/0-97/0=r2) و در محلول HCl برازش بهتری با معادله ایلوویچ (99/0-97/0=r2)  نشان داد. نتایج آنالیز نمونه­ها نشان داد غلظت فلزات سنگین اندازه گیری شده در این مطالعه در حضور بیوچار افزایش یافت ولی کمتر از غلظت مجاز در کودها بود. در نتایج آنالیز XRF رسوبات بدست آمده، بیشترین ترکیب را P2O5  (28-13%) به خود اختصاص داده است. با حضور بایوچار رهاسازی فسفر، نیتروژن و منیزیم به آب، اسید سیتریک 20 گرم بر لیتر و HCl نیم مولار بیشتر شد و حداکثر حلالیت فسفر در نسبت 25:75 کامپوزیت استرووایت/بیوچار بدست آمد. بنابراین استفاده از بیوچار ضایعات هرس انگور در فرایند رسوب استرووایت موجب افزایش حلالیت و سرعت رهاسازی فسفر می­گردد.

کلیدواژه‌ها

موضوعات

عنوان مقاله [English]

Kinetics of Phosphorus Release from Struvite/Biochar Composites Prepared from Domestic Sewage Sludge

نویسندگان [English]

  • Marziyeh Piri
  • Ebrahim Sepehr

Urmia University

چکیده [English]

Municipal wastewater is a rich source of phosphorus. Due to the limited non-renewable resources of phosphate in the world, the recovery of phosphorus from wastewater in the form of struvite or magnesium ammonium phosphate (MgNH4PO4.6H2O) as slow release fertilizer has been considered worldwide. In this study, phosphorus removal from sewage sludge with digestion-absorption process with H2SO4 (0.2 N) and the molar ratio of magnesium/ ammonium/ phosphorus in 2:1:1 at pH=8.5. The struvite and struvite/biochar composites were performed in different ratio of grape biochar to struvite including 0:100, 25:75, 50:50 and 75:25 and some of their physicochemical properties were identified. Kinetic Phosphorus release of samples were investigated at 24 hr, 3, 5, 10, 14, 28, 42, 56 and 84 days in distilled water, citric acid (20g/L) and HCl (0.5 M). The release of phosphorus, magnesium and nitrogen in the samples increased with increasing contact time. The results showed that the phosphorus-cumulative-release of composites in water and 20 g/L critic acid good fitted to the first-order kinetic model (R2 =0.97-0.99), whereas it followed the Elovich model (R2 =0.98-0.99) in 0.5 mole per liter hydrochloric acid. In addition, the analysis of samples showed that the concentration of heavy metals studied in this study, increased in the presence of biochar but were less than the allowable concentration in fertilizers. In XRF analysis, P2O5 has the highest composition of the obtained sediments. By increasing percentage of biochar the release of phosphorus, nitrogen and magnesium increased in water, citric acid 20 g/L and HCl 0.5 M and the maximum solubility of phosphorus was obtained in the ratio of 75:25 biochar to struvite. Therefore, the use of waste grape pruning biochar in the struvite deposition process increases phosphorus removal, solubility and phosphorus release rate.

کلیدواژه‌ها [English]

  • Biochar
  • domestic sewage sludge
  • phosphorus
  • struvite
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